By B. Marciniec
ISBN-10: 0080402720
ISBN-13: 9780080402727
This guide presents an up to date account of hydrosilylation reactions and the instructions within which man made and mechanistic reports in addition to functional functions of those tactics are continuing. The publication includes elements: the 1st is descriptive, providing the catalytic, mechanistic, structural and artificial points of hydrosilylation, in addition to its software in natural and organosilicon chemistry. the second one half, offered in tabular shape units out encyclopedic info relating response stipulations taken from greater than 2000 papers and patents within the interval 1965 - 1990
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Extra info for Comprehensive Handbook on Hydrosilylation
Sample text
Pyridine, chelate phosphines [183, 560, 1165, 1325]) the role of the metal is to facilitate electrophilic interactions on the hydridic hydrogen of the pentacovalent intermediate (see Scheme 56) leading to the principal formation of an α-adduct. Blustein has reported a threecomponent catalyst system containing a mixture of a copper salt, a tertiary amine and a diamine, which is mainly active in the hydrosilylation of acrylonitrile, not only by trichlorosilane but also by other hydrosilanes with less electronwithdrawing substituents such as phenyl and methyl [104, 135a, 1103].
They used the general conception of Hart and Schwartz, who assumed that the addition of hydrides to acetylenes always occurs in a eis manner, followed by isomerization of the vinylmetal compound to the trans adduct.
3. e. n+2 L M + X Y ^ LnM {X)[Y) n (78) n This reaction involves oxidation of the metal at the same time as its coordination number is increased. Generally, both the oxidation and coordination numbers are increased by two. The reverse reaction is8 termed 10a reductive elimination. e. Fe(O), Ru(O), Os(O),9 Co(I), Ir(I), Rh(I), Ni(O), Pd(O), Pt(O), Pd(II), Pt(II) as well as with the d Co(O) system. g. , , C o 2( C O ) 8 + HX i ± H C o ( C O ) 4 + X C o ( C O ) 4 (79) 4. An insertion reaction. g. amines, on the coordinated ligands (directly or by prior coordination to the metal atom) may occur and be followed by insertion.
Comprehensive Handbook on Hydrosilylation by B. Marciniec
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